Does the time difference between Moscow and Sydney change during the year?

Yes. Because of daylight saving time the gap moves between −8h and −7h.

When is the best time to call Sydney from Moscow?

Between 09:00 and 10:00 in Moscow, which is 16:00 to 17:00 in Sydney.

Moscow is 7h behind Sydney. This gap is not fixed: daylight saving time moves it between −8h and −7h during the year.

Moscow

Russia

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Sydney

Australia

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A 9-to-5 day in each city overlaps for 1h. That is 09:00–10:00 in Moscow, which is 16:00–17:00 in Sydney.

City	Time zone	UTC offset
Moscow · Russia	Europe/Moscow	UTC+3
Sydney · Australia	Australia/Sydney	UTC+10

What is the time difference between Moscow and Sydney?: Moscow is 7h behind Sydney. This gap is not fixed: daylight saving time moves it between −8h and −7h during the year.
Does the time difference between Moscow and Sydney change during the year?: Yes. Because of daylight saving time the gap moves between −8h and −7h.
When is the best time to call Sydney from Moscow?: Between 09:00 and 10:00 in Moscow, which is 16:00 to 17:00 in Sydney.